Electron induced nanoscale engineering of rutile TiO2 surfaces

Mechanism of Electron-Induced Hydrogen Desorption from Hydroxylated Rutile TiO2 (110)

The mechanism of hydrogen desorption from rutile TiO2(110)-(1 × 1) was studied by injecting electrons with controlled energy and flux into single surface hydroxyls (OH) in cryogenic scanning tunneling microscopy (STM). Desorption proceeds without a clear threshold already at much lower energies than reported previously.1 Our analysis identifies a transfer of H atoms from the TiO2 surface to the...

Surface-Induced Anisotropic Binding of a Rhenium CO2‐Reduction Catalyst on Rutile TiO2(110) Surfaces

Vibrational sum frequency generation (SFG) spectroscopy has been utilized to study the spatial orientation and alignment of Re(CO)3Cl(dcbpy) (dcbpy = 4,4′-dicarboxy2,2′-bipyridine) (or ReC0A) on the (001) and (110) surfaces of rutile single-crystalline TiO2. The SFG intensity of the CO stretching modes shows an isotropic distribution on the (001) surface and an anisotropic distribution on the (...

Nanoscale Engineering for Biomaterial Surfaces

architecture and engineering of nanoscale sculptured thin films and determination of their properties

چکیده ندارد.

High-energy electron scattering from TiO2 surfaces